Equilibrium aspects of hydrogen-induced cracking of steel stacks

Hydrogen embrittlement is a complex phenomenon, involving several length and timescales, that affects a large class of metals. Hydrogen induced cracking test tank test methods nace tm0284 astm g39 material of construction polypropylene, pvc, or glass capacities up to 55 liters cortest offers a variety of different hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on a metal sample in a hydrogen enriched. Damage due to hydrogen embrittlement and stress corrosion. Steel can be embrittled by a very small amount of hydrogen, on the level of a few parts per million.

Hydrogeninduced cracking susceptibility in highstrength. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. Hydrogen induced cracking of low strength steels in geothermal fluids keith a.

Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen. Mechanistic aspects of hydrogen induced cracking in. Equilibrium and growth characteristics of hydrogeninduced. We will now go over how to prevent hic from happening. Hic steel is plate which is tested to reduce the effects of hydrogen induced cracking in a wet h 2 s or sour service environment. Stress orientated hydrogen induced cracking sohic is a manifestation of. At such a point the crack can be considered to be in equilibrium the requirements for crack. The following paragraphs deal with this subject from a failure analysis point of view. Hydrogen embrittlement is a complex phenomenon, involving several length and. Hic testing apparatus is provided with specially made rack to keep the samples with minimum surface contact and all the specimens can be viewed during the test period easily. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. In this study, the hydrogen induced cracking was done by cathodic. Detection, characterization and sizing of hydrogen induced. Oriani 153 proposed a model where a local equilibrium of hydrogen in the traps and lattice is assumed.

The ductility loss brought about by hydrogen ingress is encountered even in unstressed bodies where such cracking is termed hydrogen induced cracking hic and is in phenomenological contrast to catastrophic failures encountered by stressed bodies. Effect of microstructure on hydrogen induced cracking behavior of a high deformability pipeline steel article in journal of iron and steel research international 2210. The threshold pressures, p, of hydrogen and of deuterium gases necessary to cause crack propagation in aisi 4340 steel of 250 ksi yield strength have been. Hydrogen cracking is also named as toe cracking or underbead cracking due to its location of occurrence. Hydrogen traps and hydrogen induced cracking in 20crmo steel. Overview of hydrogen induced cracking hic hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. It can significantly reduce the ductility and loadbearing capacity and cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Corrosionpedia explains hydrogeninduced cracking hic the mechanism of hic begins with atoms of hydrogen diffusing throughout the material. Stressoriented hydrogeninduced cracking of l360qs steel. Exposure of carbon steel equipment to wet h2s service environments can lead to various forms of attack, e.

The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. At the time these were not considered a contributory factor, as the suite of charpy impact testing and. Aug 02, 2014 the entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength. When metal is subjected to tensile stress with high level of hydrogen content, hydrogen induced cracking occurs.

Hydrogeninduced cracking also referred to as cold cracking, is caused by the diffusion of hydrogen in the crystal lattice of haz near the fusion boundary. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang. Defects hydrogen cracks in steels identification twi. An experimental and theoretical study was conducted into the kinetic and mechanical aspects of hydrogeninduced failure of metals.

By means of fracture mechanics analyses, acoustic emission techniques, and fracture surface analyses by scanning auger microscopy and xrays, it was determined how segregated phosphorus, yield strength and grain size affect the equilibrium and growth characteristics of hydrogen induced intergranular cracking in high strength steels. Hydrogen cracking of ferriticaustenitic stainless steel. This type of cracking tended to propagate with increases in the tensile strength or the diffusible hydrogen con tent of the weld metal, and in extreme cases, the cracking reached the surface a preheat and interpass. Aug 09, 2016 detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased. The occurrence of hydrogen embrittlement is a much researched phenomenon, known to cause mechanical property degradation and catastrophic failures. May 19, 2009 hic steel is plate which is tested to reduce the effects of hydrogen induced cracking in a wet h 2 s or sour service environment. In this issue, the characteristic features and principal causes of hydrogen cracks are described. The effect of hydrogen induced cracking on the integrity of steel components. Hi all, i was reading one of the articles on hydrogen induced cold cracking in steels. The effect of hydrogen induced cracking on the integrity. Hic resistant material reduces the effects of hydrogen induced cracking in a wet h 2 s or sour service environment. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. O ur last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking.

The effect of hydrogen induced cracking on the integrity of steel. Hydrogen sulfide stress corrosion cracking in materials. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. The stack ing fault energy sfe in fcc metals is thought to decrease in the. Detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased. Hydrogen traps and hydrogen induced cracking in 20crmo. Hic can be thought of as one form of hydrogen embrittlement.

Cracks can also occur in the weld bead, normally transverse to the welding direction at an angle of 45 to the weld surface. Api5lx52 steel, hydrogen induced cracking, crack growth, pipelines. Mechanisms that have been proposed to explain embrittlement include the formation of brittle hydrides. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques.

It is also called hydrogen assisted cracking hac and delayed cracking since it does not occur right after welding, but a few hours or days after the weld has completely cooled down to ambient temperature. Mechanistic aspects of hydrogen induced cracking in structural steels under hostile environments 2004 joo haengsik. Hydrogen induced cracking test instrument is supplied with standard size of 12l x 12w x 9h. Hydrogen induced cracking steel features, applications. Premature hydrogeninduced failure observed to occur in many metal systems involves three stages of fracture. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. The effect of hydrogen induced cracking on the integrity of.

Hic in welding cold cracking haz cracking moisture n org compounds r primary sources of h. Factors influencing hydrogen induced cracking welding answers. Hydrogen induced cracking hic from advanced ndt solutions. Hydrogen degradation of highstrength steel and their welded jo ints was evaluated under constant load mode in seawater.

Effect of microstructure on hydrogen induced cracking. Investigations of hydrogen embrittlement and sulfide stress cracking of nickel and nickelbase alloys have not been quite as extensive as in the case of steels. Processes or conditions involving wet hydrogen sulfide, i. Hydrogen induced cracking test for naval steels american. Weld cracking several types of discontinuities may occur in welds or. Effects of h2s partial pressure and ph of test solution on.

When the crystal lattice is in contact or is saturated with atomic hydrogen, the mechanical. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. The fracture morphology and hydrogen induced cracking can be explained by combined hydrogen embrittlement mechanisms. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. Hydrogen embrittlement in fasteners semantic scholar. By means of fracture mechanics analyses, acoustic emission techniques, and fracture surface analyses by scanning auger microscopy and xrays, it was determined how segregated phosphorus, yield strength and grain size affect the equilibrium and growth characteristics of hydrogeninduced intergranular cracking in high strength steels. Johnson 1875 on some remarkable changes produced in iron and steels by the action of hydrogen acids. A new approach to the problem of hydrogen induced cold cracking in weldments of quenched. Preventing hydrogen induced cracking welding answers. Hydrogen induced cold cracking in a low alloy steel a special test procedure was devised to permit obser vation of the precise location and the mechanism of cold cracking by w. Our last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. Hic test, hydrogen induced cracking test, step wise.

The results of the hydrogen induced cracking tests presented in this podcast can serve as a benchmark for the future development of high performance navy steels. The hydrogeninduced cracking hic susceptibility of weld met als of hightensile strength ranging from 70 to 100 kgfmm2 100 to 143 ksi was investigated to estimate the lowest possi ble preheat and interpass temperatures to prevent cracking. General aspects hydrogen embrittlement is usually understood as the unwanted delayed brittleness of. Based on the estimation of the critical hydrogen pressure and concentrations required for hydrogeninduced delayed cracking in highstrength steel, the conclusion that welded joints are hydrogen pressure microcracks body can be drawn under certain conditions. Josephicf the threshold pressures, p, of hydrogen and of deuterium gases necessary to cause crack propagation in aisi 4340 steel of 250 ksi yield strength have been determined as functions of planestrain stress intensity factor k. Understanding and mitigating hydrogen embrittlement of steels core. In cmn steels, the crack will normally originate in the heat affected zone haz, but may extend into the weld metal fig 1. Features of hydrogen induced cracking hic steel masterhic is masteel uk limiteds designation for hic steel for fine grain pressure vessel steels.

Fundamentals of hydrogen embrittlement in steel fasteners s. General aspects hydrogen embrittlement is usually understood as the unwanted delayed brittleness of a material fig. Cracking occurs due to a significant loss in ductility. Hydrogen embrittlement in power plant steels citeseerx. Unlike other modes of environmentallyassisted cracking, such as stress corrosion cracking, cracks caused by hydrogen embrittlement usually do not branch. It should be noted that there exists some degree of uncertainty as to the shape of the curve in fig. Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. Hydrogen effect is greater near room temperature and decreases with increasing strain rate. Lichti, david m firth and annette d karstensen mpt solutions, po box 310, lower hutt, new zealand k.

Mechanistic aspects of hydrogen induced cracking in structural steels under hostile environments. Understanding and mitigating hydrogen embrittlement of. The objective of this thesis is to investigate the resistance of l80 erw and seamless steel pipe, with five different chemical compositions, to both hic and ssc. Brahimi introduction high strength mechanical steel fasteners are broadly characterized by tensile strengths in the range of 1,000 2,000 mpa 150 300 ksi, and are often used in critical applications such as in. In this study, the potential susceptibility of three leanalloyed metastable tripaided ferriticaustenitic stainless steels to hydrogeninduced. The role of hydrogen in the welding of steel duration. Hydrogen induced cracking tests of high strength steels. Although hydrogen induced cracks are found to initiate at the elongated inclusions, only longitudinal cracks were observed in this study which is not detrimental to the embrittlement. Casing pipes used in sour service are prone to two forms of failure. With the increasingly serious problem of hydrogen sulfide corrosion, the development of antisulfur seamless pipeline is imminent, and the performance of sulfurresistant is. I crack initiation, 2 stable slow crack growth, and 3 unstable rapid crack growth.

Corrosionpedia what is hydrogeninduced cracking hic. Sep 07, 2009 the methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Hydrogen cracking its causes, costs and future occurrence p h m hart weld metal hydrogen cracking in pipeline girth welds, proc. Hic test, hydrogen induced cracking test, step wise cracking. Carbon seamless steel pipe is mainly used for conveying highpressure oil and gas near the wellhead. Hydrogeninduced cracking hic is a far too common type of failure. Masterhic is masteel uk limiteds designation for hic steel for fine grain pressure vessel steels offering specific and superior properties for sour gas application. Equilibrium aspects of hydrogeninduced cracking of steels. Factors influencing hydrogen induced cracking welding. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Hydrogen embrittlement characteristics, especially pertinent to sulfide stress cracking, or steels has been investigated to a great extent. Hughes 1880 note on some effects produced by the immersion of steel and iron wires in acidulated water.

The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Hydrogen induced cracking steel features, applications and. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang dept. Hydrogen induced cracking of carbon seamless pipe materials. Hydrogen traps and hydrogen induced cracking in 20crmo steel wei li,1,2 xu zhu,1 jianjun yao,3 xuejun jin1,2 and xifan ding4 1 institute of advanced steels and materials, school of materials science and engineering, shanghai jiao tong university, shanghai, 200240 china. Hydrogen cracking its causes, costs and future occurrence. Hydrogen induced cracking tests of high strength steels and. Josephic p h 1974 equilibrium aspects of hydrogen induced cracking of steels. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Despite a large research effort in attempting to understand the mechanisms of. Although hydrogen induced cracks are found to initiate at the elongated inclusions, only longitudinal cracks were observed in this study which is not detrimental to. Despite a large research effort in attempting to understand the mechanisms of failure. The european pipeline research group eprg has initiated a project to compare full scale hydrogen induced cracking hic test results 1sided exposure with laboratory hic test results 6sided exposure of the same materials with a view to generating acceptance criteria for sweet service steels that could be applied to milder sour conditions.

Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Formation mechanism of hydrogeninduced delayed cracking. This hydrogen may come from some of the many sources described above. Hydrogen induced stress cracking hisc resistance and.

Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Hydrogen induced cracking of low strength steels in. Hydrogen induced stress cracking hisc resistance and improvement. Hydrogeninduced delayed cracking in tripaided lean.

Stress oriented hydrogen induced cracking sohic behavior of heat affected zone haz of l360mcs steel in wet h2s environment was studied by separating crack, sem and eds. Premature hydrogen induced failure observed to occur in many metal systems involves three stages of fracture. Davies, formation and analysis of stack cracks in a pipeline steel, j. Susceptibility to sohic for linepipepressure vessel steels twi. Hydrogen induced cold cracking in a low alloy steel. Through the analysis of the relationship between the microstructure evolution of welded joints, diffusion enrichment of hydrogen and. The microstructure of the steel also exhibited nitride precipitates within the ferrite grains. This is the typical fracture morphology caused by hic. An experimental and theoretical study was conducted into the kinetic and mechanical aspects of hydrogen induced failure of metals. Hydrogen cracking may also be called cold cracking or delayed cracking. The ductility loss brought about by hydrogen ingress is encountered even in unstressed bodies where such cracking is termed hydrogen induced cracking hic and is in phenomenological contrast to catastrophic failures encountered by stressed bodies subjected to hydrogen producing environments. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. Understanding and mitigating hydrogen embrittlement of steels.